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Insights into the Decomposition of Olefin Metathesis Precatalysts

✍ Scribed by Manzini, Simone; Poater, Albert; Nelson, David J.; Cavallo, Luigi; Slawin, Alexandra M. Z.; Nolan, Steven P.

Book ID
124070459
Publisher
John Wiley and Sons
Year
2014
Tongue
English
Weight
700 KB
Volume
53
Category
Article
ISSN
0044-8249

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## Abstract The mechanism of the __trans__ to __cis__ isomerization in Ru complexes with a chelating alkylidene group has been investigated by using a combined theoretical and experimental approach. Static DFT calculations suggest that a concerted single‐step mechanism is slightly favored over a mu