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Insights into the Catalytic Mechanisms of Phenylalanine and Tryptophan Hydroxylase from Kinetic Isotope Effects on Aromatic Hydroxylation †

✍ Scribed by Pavon, Jorge Alex; Fitzpatrick, Paul F.

Book ID
126192974
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
108 KB
Volume
45
Category
Article
ISSN
0006-2960

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## Abstract Deuterium, solvent, and ^15^N kinetic isotope effects have been used to probe the mechanisms by which flavoproteins oxidize carbon–oxygen and carbon–nitrogen bonds in amines, hydroxy acids, and alcohols. For the amine oxidases D‐amino acid oxidase, __N__‐methyltryptophan oxidase, and tr