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Inside Cover: Synthesis and Structural Characterization of Crystalline Nonacenes (Angew. Chem. Int. Ed. 31/2011)

✍ Scribed by Dr. Balaji Purushothaman; Matthew Bruzek; Dr. Sean R. Parkin; Prof. Anne-Frances Miller; Prof. John E. Anthony

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 663 KB
Volume: 50
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.201104289

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✦ Synopsis

Nonacene crystals …

… possess a bright metallic sheen and their solution absorption spectra fit well in the series of silylethyne-substituted acenes. As J. E. Anthony et al. report in their Communication on page 7013 ff., crystallographic analysis of functionalized nonacenes confirmed the nine-ringed structure and showed that p-stacked arrangements exist in the solid state. EPR analysis showed that the nonacenes possess radical character, and exposure of nonacene solutions to light caused decomposition to form a red-fluorescent compound.

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