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Inside Cover: Direct Monitoring of Formation and Dissociation of Individual Metal Complexes by Single-Molecule Fluorescence Spectroscopy (Angew. Chem. Int. Ed. 18/2007)

✍ Scribed by Alexander Kiel; Janos Kovacs; Andriy Mokhir; Roland Krämer; Dirk-Peter Herten

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
33 KB
Volume
46
Category
Article
ISSN
0044-8249

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✦ Synopsis

Single‐molecule spectroscopy has proven a versatile tool in biochemistry and molecular biology. In their Communication on page 3363 ff., D. P. Herten et al. describe the first application of this technique to chemical reactions of small molecules by observing the association and dissociation of a Cu^2+^ complex in real time. By the use of confocal microscopy and by designing a fluorescent metal sensor that can be immobilized on glass slides, they were able to obtain the kinetics of individual complexes in thermodynamic equilibrium.

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Direct Monitoring of Formation and Disso
Direct Monitoring of Formation and Dissociation of Individual Metal Complexes by Single-Molecule Fluorescence Spectroscopy
✍ Alexander Kiel; Janos Kovacs; Andriy Mokhir; Roland Krämer; Dirk-Peter Herten 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 32 KB 👁 2 views

The authors of this Communication have noticed that Equation (2) appears incorrectly in print. The authors apologize for the oversight, but point out that this mistake has no bearing on the discussion of their results as the correct equation [Eq. ( 2)] was used in their calculations.