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Insertion reactions of the p-complex structure of silylenoid into C–X bonds (X

✍ Scribed by Yuhua Qi; Zonggang Mu; Yanxia Zhang; Dacheng Feng


Book ID
106538576
Publisher
Springer
Year
2010
Tongue
English
Weight
321 KB
Volume
21
Category
Article
ISSN
1040-0400

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Insertion reactions of thermally generat
✍ Lutz-Werner Gross; Rainer Moser; Wilhelm P. Neumann; Karl-Heinz Scherping 📂 Article 📅 1982 🏛 Elsevier Science 🌐 French ⚖ 239 KB

Thermally generated stannylenes R2Sn insert efficiently into Sn-X bonds (X = Cl, Br, SPh) as well as into electron deficient Sn-Sn bonds e.g. in Me2(Hal)Sn-Sn(Hal)Me2, but not into hexaalkyldistannanes R6Sn2 under the same conditions; stannylenes R2Sn always behave as nucleophiles here. During our s