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Insertion of Terminal and Internal Acetylenes into the Zr−μ-Methylene Bond of the Dinuclear Cationic Zirconium Complex [{Zr(η 5 -C 5 H 5 )} 2 (μ-CH 2 )(μ-Cl)(μ-η 5 -C 5 H 4 -η 5 -C 5 H 4 )][BMe(C 6 F 5 ) 3 ]. Synthetic Aspects, NMR Spectroscopic Study, and Dynamic Behavior in Solution

✍ Scribed by Royo, Eva; Royo, Pascual; Cuenca, Tomás; Galakhov, Mikhail


Book ID
126028424
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
143 KB
Volume
19
Category
Article
ISSN
0276-7333

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Synthesis, Structural Characterisation a
✍ Antonio Antiñolo; Iván Dorado; Mariano Fajardo; Andrés Garcés; Isabel López-Sol 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 254 KB 👁 1 views

## Abstract The preparation of a family of dinuclear monocyclopentadienyl imidoniobium and ‐tantalum complexes was achieved by two different synthetic routes. The diimido complexes [{M(Cp′)Cl~2~}~2~(μ‐1,__i__‐NC~6~H~4~N)] [Cp′ = η^5^‐C~5~H~4~SiMe~3~, M = Nb, __i__ = 4 (1); Cp′ = η^5^‐C~5~H~4~SiMe~3