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Insertion of Reactive Rhodium Carbenes into Boron–Hydrogen Bonds of Stable N-Heterocyclic Carbene Boranes

✍ Scribed by Li, Xiben; Curran, Dennis P.


Book ID
120776175
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
630 KB
Volume
135
Category
Article
ISSN
0002-7863

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## Abstract The reaction of 2‐[^13^C]‐1‐ethyl‐3‐isopropyl‐3,4,5,6‐tetrahydropyrimidin‐1‐ium hexafluorophosphate ([^13^C~1~]‐1‐PF~6~) with a slight excess (1.03 equiv) of dimeric potassium hexamethyldisilazide (“(K‐HMDS)~2~”) in toluene generates 2‐[^13^C]‐3‐ethyl‐1‐isopropyl‐3,4,5,6‐tetrahydropyrim