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Insertion of isocyanides into ReC bonds

✍ Scribed by John J. Alexander; Laura L. Padolik; Douglas M. Ho


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
617 KB
Volume
240
Category
Article
ISSN
0020-1693

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The (amido)methyl complexes [Ta(η 5 -C 5 Me 5 )(NtBu)-Me(NR 2 )] [R = Ph (3), SiMe 3 (4)] were prepared by reaction of [Ta(η 5 -C 5 Me 5 )(NtBu)ClMe] (1) with the appropriate lithium amides. Attempts to isolate the analogous NHMe derivative afforded a mixture of complexes [Ta(η 5 -C 5 Me 5 )(NtBu)-M