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Insertion of Fischer Carbene Complexes into the Carbon-Carbon Bond of 1,2-Diphenylcyclopropenone: Formation of Cyclobutenones and o- and p-Methoxyphenol Derivatives

✍ Scribed by Zora, Metin; Herndon, James W.


Book ID
126125436
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
434 KB
Volume
13
Category
Article
ISSN
0276-7333

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CCα Insertion: Insertion of an Alkyne in
✍ Seda Ünaldi; Rudolf Aumann; Roland Fröhlich 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 292 KB 👁 1 views

## Abstract The first examples of insertion of a CC bond of an alkyne into a C~carbene~C~__α__~ single bond of a carbene complex (CC~__α__~ insertion) are reported. (__prim‐__Alkyl)carbene complexes [(OC)~5~MC(OEt)CH~2~R] (1 a–f; M=Cr, W; R=__n__Pr, C~7~H~7~, Ph) undergo CC~__α__~ insertion of