Insertion of an acetylene into the platinum-tin bond of (PEt3)2(SnCl3)2(.mu.-Cl)2Pt2
β Scribed by Clark, Howard C.; Ferguson, George; Goel, Anil B.; Ruhl, Barbara L.
- Book ID
- 127390880
- Publisher
- American Chemical Society
- Year
- 1984
- Tongue
- English
- Weight
- 758 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0276-7333
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π SIMILAR VOLUMES
The reaction pathway for the insertion reaction of SnCl into the Pt-Cl 2 Ε½ . Ε½ . bond on the cis-Pt Cl PH compound was investigated at the ab initio MO level of 2 3 2 theory. The optimized structure obtained for the transition state indicates that this reaction proceeds through a three-center transi
Quantum-mechanical calculations were carried out at the MP4(SDQ)//MP2 level of theory to determine the energies and reaction mechanism for the carbonyl insertion reaction (second step in the olefin hydroformylation catalytic cycle), using a heterobimetallic Pt(SnCl 3 )(PH 3 ) 2 (CO)(CH 3 ) compound