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Insertion of an acetylene into the platinum-tin bond of (PEt3)2(SnCl3)2(.mu.-Cl)2Pt2

✍ Scribed by Clark, Howard C.; Ferguson, George; Goel, Anil B.; Ruhl, Barbara L.


Book ID
127390880
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
758 KB
Volume
3
Category
Article
ISSN
0276-7333

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The reaction pathway for the insertion reaction of SnCl into the Pt-Cl 2 Ε½ . Ε½ . bond on the cis-Pt Cl PH compound was investigated at the ab initio MO level of 2 3 2 theory. The optimized structure obtained for the transition state indicates that this reaction proceeds through a three-center transi

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