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Insertion of a stable dialkylsilylene into silicon-chlorine bonds

✍ Scribed by Shintaro Ishida; Takeaki Iwamoto; Chizuko Kabuto; Mitsuo Kira


Book ID
111611553
Publisher
Springer
Year
2003
Tongue
English
Weight
79 KB
Volume
2
Category
Article
ISSN
1569-0660

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Addition of a stable dialkylsilylene to
✍ Shintaro Ishida; Takeaki Iwamoto; Mitsuo Kira 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 163 KB

## Abstract The reactions of an isolable dialkylsilylene, 2,2,5,5‐tetrakis(trimethylsilyl)silacyclopentan‐1,1‐diyl (**1**) with ethylene, (Z)‐2‐butene, acetylene, bis(trimethylsilyl)acetylene, and 2,3‐dimethylbutadiene at room temperature gave the corresponding silacycles as isolable compounds. Bec