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Insertion into metal—carbon and hydrogen—carbon bonds; synthesis of group VIA metal cyclopentadienylcarbonyl metallates and hydrides

✍ Scribed by S.A. Keppie; M.F. Lappert

Book ID
108347283
Publisher
Elsevier Science
Year
1969
Tongue
English
Weight
130 KB
Volume
19
Category
Article
ISSN
0022-328X

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✍ Dr. Yun Xiong; Dr. Shenglai Yao; Prof. Dr. Matthias Driess 📂 Article 📅 2012 🏛 John Wiley and Sons 🌐 English ⚖ 270 KB

The facile one-pot reaction of the stable N-heterocyclic silylene LSi: 1 (L=(ArN)C(=CH(2))CH=C(Me)(NAr), Ar=2,6-iPr(2)C(6)H(3)) with Me(2)Zn, Me(3)Al, H(3)Al-NMe(3), and MeLi has been investigated. The silicon(II) atom in 1 is capable of insertion into the corresponding M-C and Al-H bonds under very