A total of ten C18 fatty esters containing an azido group and another chemical function (ethylenic, bromo, epoxy, hydroxy, methoxy, acetoxy or vinyl) were synthesised from methyl ricinoleate. Methyl di-and triazidooctadecanoate were also derived from methyl oleate and ricinolcate, respectively. The
Insecticidal action of some esters of halogenated fatty acids in the vapor phase
โ Scribed by R.C. Roark; R.T. Cotton
- Publisher
- Elsevier Science
- Year
- 1928
- Tongue
- English
- Weight
- 50 KB
- Volume
- 206
- Category
- Article
- ISSN
- 0016-0032
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โฆ Synopsis
THE action of the esters of some of the halogenated fatty acids in the vapor phase upon insects was tested. From the standpoints of toxicity to insects, availability, cost, and freedom from fire hazard, methyl, isopropyl, and ethyl monochloroacetates appear to be the most promising of the lower alkyl esters of chloroformic (chlorocarbonic), monochloro-, dichloro-, and trichloroacetic, monobromoacetic, alpha-bromo-and beta-bromopropionic and beta-chloropropionic acids tested. Dosages of I pound of methyl monochloroacetate, 1.5 pounds of isopropyl monochloroacetate, and 2 pounds of ethyl monochloroacetate per I,OOO cubic feet were effective against stored-product insects in fumigation vaults of the commercial type. As further tests, however, showed that the monochloroacetates injure the germination of wheat, these fumigants do not look promising for the fumigation of grain intended for seed.
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The electron impact (EI) mass spectral analysis of the picolinyl esters of nine positional isomers of conjugated diacetylenic fatty acids showed prominent M + and [M-l] + peaks. In all cases there was a regular series of ions 14 amu apart in the high molecular weight range until the triple bond syst