## Abstract For Abstract see ChemInform Abstract in Full Text.
Inorganic Polysulfanes H2Sn with n > 1
β Scribed by Ralf Steudel
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 46 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
For Abstract see ChemInform Abstract in Full Text.
π SIMILAR VOLUMES
The gas-phase acidities βG acid (298 K) of the sulfanes H 2 S n may be compared to those of other strong BrΓΈnsted acids like gaseous HNO 2 (1396), HCl (1371), and HBr (1332). The (n = 1-4) have been calculated by ab initio molecular orbital theory using the G2 and G2(MP2) methods, which were monoani
The preparation of seven novel organic polysulfanes is reported. Bis(n-octyl)heptasulfane R 2 S 7 1 is formed upon reaction of RSCl with [Cp 2 TiS 5 ], while the corresponding nonasulfane R 2 S 9 2 is obtained by reaction of RSSCl with [Cp 2 TiS 5 ]. The bis(n-octyl)pentasulfane R 2 S 5 3 is obtaine
The rate data for the Menschutkin reaction between strongly activated Z-substituted benzyl ptoluenesulfonates and Y-substituted N,N-dimethylanilines in acetonitrile at 35 Β°C fit the equation, , which is consistent with concurrent first-and second-order processes. The k 1 and k 2 values for each sub