## Abstract Polychloro‐alkanes, including dichloromethane (CH~2~Cl~2~), chloroform (CHCl~3~) and tetrachloromethane (CCl~4~), were first introduced to synthesize trigonal selenium (t‐Se) microrods as a new kind of coordinating solvent, which played two important roles in the formation of Se nuclei
Inorganic and organic templates-assisted solvothermal synthesis of trigonal selenium microrods
✍ Scribed by Jianmin Ma; Chuansheng Sun; Jiabiao Lian; Wenjun Zheng
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 837 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0232-1300
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✦ Synopsis
Abstract
A facile and environment‐friendly solvothermal method has been developed for the controlled growth of nano‐ and micro‐structured trigonal selenium (t‐Se) by using green templates. And, the morphology of trigonal selenium can be tuned by using different kinds of templates. The as‐obtained products were characterized by X‐ray powder diffraction (XRD) and scanning electron microscope (SEM). Furthermore, the formation mechanism of trigonal selenium nano‐ and microcrystals was rationally suggested. This method will open a new avenue to synthesize other functional inorganic nano‐ and microcrystals. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
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