Inner-Sphere Cluster Formation by [Ru(NH 3 ) 5 H 2 O] 3+ or [Os(NH 3 ) 5 H 2 O] 3+ in Combination with [M(CN) 6 ] 4- (M = Fe, Ru, or Os)
β Scribed by Poulopoulou, Vassiliki G.; Taube, Henry; Nunes, Fabio S.
- Book ID
- 127270801
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 98 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0020-1669
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## Abstract The kinetics of substitution of H~2~O by Ru(NH~3~)~5~pz^2+^ (pz = pyrazine) in Fe(CN)~5~H~2~O^3β^ have been studied in micellar aqueous solutions of sodium dodecylsulfate (SDS). Experimental results are discussed by using an approach based on the transitionβstate theory. This approach i