𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Initiator efficiency of peroxides in high-pressure ethene polymerization

✍ Scribed by Philipp Becker; Michael Buback; Johannes Sandmann


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
181 KB
Volume
203
Category
Article
ISSN
1022-1352

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Initiator Efficiency of tert-Alkyl Perox
✍ Michael Buback; Bart Fischer; Stefan Hinrichs; Stephan Jauer; John Meijer; Johan 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 313 KB

## Abstract High‐pressure ethene polymerizations using thirteen __tert__‐alkyl peroxyester initiators, RC(CH~3~)~2~OOCOR′ (with R = methyl, ethyl, __neo__‐pentyl, __tert__‐butyl and R′ = methyl, __i__‐propyl, propyl, butyl, __tert__‐butyl, 2‐heptyl) have been carried out in a CSTR. The initiat

Deactivation Kinetics of Metallocene-Cat
✍ Hans Peter Dornik; Gerhard Luft; Alexander Rau; Thomas Wieczorek 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 108 KB

## Abstract Summary: The kinetics of ethene polymerization with metallocene/[Me~2~PhNH]^+^[B(C~6~F~5~)~4~]^−^/Al^__i__^Bu~3~ (ternary systems) and metallocene/methylaluminoxan (MAO) systems respectively has been investigated at 100–140 °C and 7 MPa. Overall, eight different unbridged and __ansa__‐m

Modeling of high-pressure ethylene polym
✍ B. Cerinski; J. Jelencic 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 119 KB 👁 2 views

## Abstract A kinetic model of a high‐pressure, free‐radical ethylene polymerization is presented. The model of S. Goto, K. Yamamoto, S. Furui, and M. Sugimoto (J Appl Polym Sci, Appl Polym Symp 1981, 36, 21), developed for several common peroxides, was extended to be applicable for the oxygen init

Non-ideality in vinyl polymerization—VI:
✍ P.C. Deb; S.K. Kapoor 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 217 KB

The polymerization of methyl methacrylate in benzene was initiated by benzoyl peroxide and examined by kinetic analysis particularly from the point of view of primary radical termination. It is concluded that the velocity constant for dissociation of the benzoyloxy radical to give the phenyl radical