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Initiation of cationic polymerization by electron transfer: Polymerization of n-vinyl carbazole by hexachloroantimonate (SbCl6−) ion

✍ Scribed by G.W. Cowell; K. Kocharyan; A. Ledwith; J.H. Woods

Publisher
Elsevier Science
Year
1970
Tongue
English
Weight
346 KB
Volume
6
Category
Article
ISSN
0014-3057

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Cationic polymerization of N-vinyl carba
Cationic polymerization of N-vinyl carbazole by trityl salts—I.: Reactivity of propagating species
✍ Matilde Rodriguez; L.M. León 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 308 KB

Abstract~The cationic polymerization of N-vinyl carbazole, initiated by Ph3 C+ AsF6 and Ph3C + PF2 in methylene dichloride at 20 and 0 °, has been studied in some detail. Reactions were very fast and rates of monomer consumption were measured using an adiabatic calorimetric technique. Initiation was