Initiation Efficiency in the Synthesis of Molecular Brushes by Grafting from via Atom Transfer Radical Polymerization
β Scribed by Sumerlin, Brent S.; Neugebauer, Dorota; Matyjaszewski, Krzysztof
- Book ID
- 118032382
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 130 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0024-9297
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Materials scientists, polymer chemists, surface physicists and materials engineers will find this book a complete and detailed treatise on the field of polymer brushes, their synthesis, characterization and manifold applications. In a first section, the various synthetic pathways and different surfa
## Abstract Hydrophilic polymer brushes grown via surfaceβinitiated ATRP from silicon oxide surfaces are susceptible to detachment via hydrolytic cleavage of the anchoring siloxane bond. This paper investigates the influence of the structure of the ATRP initiator on the stability of these brushes a