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Initial-state and transition-state solvent effects on reaction rates and the use of thermodynamic transfer functions

✍ Scribed by Buncel, Erwin; Wilson, Harold


Book ID
127123374
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
934 KB
Volume
12
Category
Article
ISSN
0001-4842

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Solvent effect on the initial state and
✍ Olga A.; JΓ‘n Benko; Ol'ga VollΓ‘rovΓ‘; Vladislav Holba πŸ“‚ Article πŸ“… 1993 πŸ› Springer 🌐 English βš– 257 KB

Solvent effects on rate constants and activation enthalpies and entropies for the anation of [Cr(NH3)sH20] 2+ by SCN-in aqueous mixtures of MeOH, EtOH, i-PrOH and t-BuOH were analysed into initial and transition state contributions. From kinetic measurements, solubilities of the complex salt and ent