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Inhibition of radical polymerization by nitroxide mono- and biradicals

✍ Scribed by L.V. Ruban; A.L. Buchachenko; M.B. Neiman; Yu.V. Kokhanov

Book ID
118357400
Publisher
Elsevier Science
Year
1966
Weight
291 KB
Volume
8
Category
Article
ISSN
0032-3950

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An Improved Catalytic Method for Alkoxya
An Improved Catalytic Method for Alkoxyamine Synthesis – Functionalized and Biradical Initiators for Nitroxide-Mediated Radical Polymerization
✍ Marc Bothe; Gudrun Schmidt-Naake 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 89 KB

## Abstract Mn(salen)Cl was applied as a low‐cost catalyst for the formation of alkoxyamines from nitroxides and substituted styrenes. These “unimolecular initiators” for nitroxide‐mediated radical polymerization (NMRP) were synthesized using 2,2,6,6‐tetramethyl‐1‐piperidine‐1‐oxyl and 2,2,5‐trimet