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Inhibition of Lysine 2,3-Aminomutase by the Alternative Substrate 4-Thialysine and Characterization of the 4-Thialysyl Radical Intermediate

โœ Scribed by Jennifer Miller; Vahe Bandarian; George H. Reed; Perry A. Frey


Book ID
115568675
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
126 KB
Volume
387
Category
Article
ISSN
0003-9861

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Formation of semiquinone radical in the
โœ Ravi Joshi; Tapan K. Ghanty; Tulsi Mukherjee ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 638 KB

Embelin, 2,5-dihydroxy-3-undecyl-1,4-benzoquinone, has two intra-molecular hydrogen bonds between the quinone and hydroquinone groups present on the same ring. Therefore, it is expected to produce semiquinone radical in the oxidation as well reduction reactions. To investigate this aspect, kinetics