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Inherent Asymmetry of Constitutionally Equivalent Methyl Groups in the H/D Equilibration of n- and i-C3H7Fe(OH)+ Complexes

✍ Scribed by Claudia Trage; Waltraud Zummack; Detlef Schröder; Helmut Schwarz


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
81 KB
Volume
40
Category
Article
ISSN
0044-8249

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The structure of 1 is built up from FeMo 12 (H 2 PO 4 ) 6 (PO 4 ) 2 (OH) 6 O 4؊ 24 cluster anions connected to each other via hydrogen bonds. The arrangement of clusters is such that each cluster is surrounded by six equivalent anions resulting in three-dimensional cavities. The charge balancing cat