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Inhaltsstoffe des Osmanthus-Absolues. 2. Mitteilung: 2,7-Epoxy-megastigma-4,8(E)-dien

✍ Scribed by Roman Kaiser; Dietmar Lamparsky

Publisher
John Wiley and Sons
Year
1978
Tongue
German
Weight
228 KB
Volume
61
Category
Article
ISSN
0018-019X

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✦ Synopsis

Constituents of Osmanthus Absolute, 2nd communication: 2,7‐Epoxy‐megastigma‐4,8 (E)‐diene

The characteristic fragmentation pattern in the mass spectrum of 2,7‐epoxy‐dihydro‐α‐ionone bearing a new oxabridged ionone skeleton has lead to the identification of a further trace component in Osmanthus absolute, the 2,7‐epoxy‐megastigma‐4,8(E)‐diene. The synthesis was performed in three steps starting from the above mentioned new ionone derivative now synthetically available by base treatment of 2‐hydroxy‐α‐ionone [1].

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