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Infrared study of the state of water in the hydration shell of DNA

✍ Scribed by Falk, Michael; Poole, A. G.; Goymour, C. G.


Book ID
120174880
Publisher
NRC Research Press
Year
1970
Tongue
French
Weight
339 KB
Volume
48
Category
Article
ISSN
0008-4042

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πŸ“œ SIMILAR VOLUMES


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✍ N. J. Tao; S. M. Lindsay; A. Rupprecht πŸ“‚ Article πŸ“… 1989 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 702 KB

## Synopsis We have used Raman scattering to study the water 0-H stretching modes at -3450 and -3220 cm-' in DNA films as a function of relative humidity (r.h.). The intensity of the 3220-cm-' band vanishes 88 the r.h. is decreased from 98% to around 80%, which indicates that the hydrogen-bond net

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High-resolution \*H-nmr is employed to monitor the D20 in hydrated solids of Li-DNA prepared from solution by three different methods: lyophilization, slow evaporation of the water, and wet spinning in alcohol. From the spectral shapes and spin-spin relaxation measurements, the DNA in the lyophilize