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Infrared studies of the interaction of chromium hexacarbonyl and molybdenum hexacarbonyl with high-surface-area spinel

✍ Scribed by C.Mas Carbonell; C.Otero Areán

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
305 KB
Volume
5
Category
Article
ISSN
0924-2031

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The reaction of Mo(CO) 6 with thin films of dehydroxylated alumina grown on a Mo(1 0 0) substrate above 500 K is studied in ultrahigh vacuum using temperature-programmed desorption and Auger and X-ray photoelectron spectroscopies. This results in the formation of a molybdenum carbide that incorporat