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Infrared spectroscopy of rovibrational transitions of methyl radicals (CH3, CD3) in solid parahydrogen

✍ Scribed by Hiromichi Hoshina; Mizuho Fushitani; Takamasa Momose

Book ID
113726532
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
461 KB
Volume
268
Category
Article
ISSN
0022-2852

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Photolysis of methyl iodide in solid parahydmgen crystal at about 5 K by a low-pressure mercury lamp produces methyl radical, methane and ethane as evidenced by their infrared absorption spectra. It is found that even after the complete depletion of methyl iodide the intensity of the ~' 3 and v 4 ba