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Infrared spectroscopy of organometallic ions in the gas phase: From model to real world complexes

✍ Scribed by Luke MacAleese; Philippe Maître

Book ID
102943493
Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
623 KB
Volume
26
Category
Article
ISSN
0277-7037

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✦ Synopsis

Abstract

Gas phase mid‐infrared spectroscopy of molecular ions can nowadays be performed with high performance mass spectrometers coupled to free electron lasers (FEL). The wide and continuous tunability of highly intense FELs in the mid‐infrared region can be exploited for performing infrared multiple photon dissociation (IRMPD) spectroscopy of molecular ions. This review will focus on gas phase IRMPD spectroscopic investigations aiming at probing the structure and the reactivity of transition metal complexes. The performance of infrared spectroscopy for characterizing the coordination mode of polydentate ligands and the spin state of the metal will be illustrated. Infrared spectroscopy has also been exploited to probe the reactivity of metal complexes, and a special attention will be given to the infrared spectroscopy of reactive intermediates. © 2007 Wiley Periodicals, Inc., Mass Spectrom. Rev.

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