Infrared spectra of HCl, HBr and HI dissolved in liquid xenon
✍ Scribed by J. Perez; S. Velasco; J.A. White; A.Calvo Hernández
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 195 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0167-7322
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Calculations of far-infrared spectra for the weakly bound complexes (HF),, (HCI), and (HBr), are reported. For (HF), and (HCl)z, potentials fitted to ab initio data are used. Spectra are also predicted using simple classical electrostatic potentials. The method involves diagonalising the Hamiltonian
The fundamental infrared spectra (2700-3100 cm-') of dilure solutions of HCI in liquid SF, at temperatures between 2 18 and 316 K have been calculated by applying a spectral theory based on the decomposition of the rotational motion of the diatomic molecule into two limiting cases: quasi-free rotati
The spectra of HCl and DC1 molecules trapped in 3 nitrogen matrix were studied in the 100~250cm-L spectral region. Two absorptions were observed for each species: at 154 and 207cm-L for EfCL and at 132 and 162cm-1 for DCI. These &sorption showed monomeric behaviour. They are 'assigned to librationtr