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Infrared spectra of deuterated α-amino acids NH3+CDRCOO: Assignment of the absorption bands of α-alanine

✍ Scribed by Shigeko Suzuki; Tairo Ohshima; Nobuo Tamiya; Kunio Fukushima; Takehiko Shimanouchi; San-Ichiro Mizushima


Publisher
Elsevier Science
Year
1959
Weight
401 KB
Volume
15
Category
Article
ISSN
0371-1951

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✦ Synopsis


C-cleuteratecl a-amino acids NH,+CDRCOO-were prepared by electrolytic reduction and enzymic methods. The i&a-red spectra of these substances were measured and the comparison of the results with those obtained for non-deuterated and N-deuterated compounds enabled us to assign the infra-red bands.


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The infrared absorption spectra of the wavenumber regions including the n 3 and n 2 fundamental bands of DN 3 have been recorded with a spectral resolution of 0.003 cm 01 . In the region between 1105 and 1311 cm 01 the transitions observed are due to n 3 and the overtone band 2n 6 and in the region