Infrared spectra of complexes of Rh(I), Ir(I), Ru(II), and Os(II), containing molecular nitrogen
β Scribed by Yu. G. Borod'ko; S. M. Vinogradova; Yu. P. Myagkov; D. D. Mozzhukhin
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 1970
- Tongue
- English
- Weight
- 355 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0022-4766
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The spectra of the title compounds have been recorded and interpreted. On this basis, the structures of the anhydrous compounds Be(OOCH)\*, Be(OOCMe),, Zn(OOCMe), are predicted to have tetrahedral coordination with the carboxylate ions acting as bidentate ligands.
The generation of singlet oxygen by a photochemical pathway, involving the excited state of a pentaammine Ru(II) complex ,:ontaining an N-substituted 4-cyanopyridine ligand and molecular oxygen in aqueous solution, is reported in this work. A :wo-step degradation process occurs by virtue of the acti