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Infrared spectra and enolization of simple 1, 3-diketones

✍ Scribed by E. Ya. Gren; A. K. Grinvalde; G. Ya. Vanag


Publisher
Springer US
Year
1967
Tongue
English
Weight
347 KB
Volume
6
Category
Article
ISSN
0021-9037

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## Abstract The keto–enol tautomerism of 3‐chloro‐pentane‐2,4‐dione (ClPD) was studied in aqueous micellar solutions of cationic, anionic, and nonionic surfactants. The enol of ClPD tautomerizes rapidly in water to the equilibrium proportions of the keto form, __K__~E~=0.55; whereas the keto–enol c