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Infrared multiphoton decomposition of highly excited t-butyl chloride-d9

✍ Scribed by Robertd McAlpine; Glenn A. McRae; J. W. Goodale

Book ID: 102928031
Publisher: John Wiley and Sons
Year: 1994
Tongue: English
Weight: 573 KB
Volume: 26
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550260203

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✦ Synopsis

The infrared multiphoton decomposition (IR MPD) of t-butyl chloride-dg as a function of pressure and fluence is reported. The major decomposition route was molecular elimination of DCI in accord with earlier pyrolysis studies. The effect of added gases (2-methyl prOpene-d8, DC1 and 2-methyl propene-h8) on the MPD is presented. This study is a further example of the utility of a new method of analysis of MPD experiments.

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