Infrared matrix and microwave spectroscopy of the gas phase vinylchloride-ozone reaction
✍ Scribed by S. Vaccani; H. Kühne; A. Bauder; Hs.H. Günthard
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 230 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
The g.xs phase olonoiysis of vinylchlorlde has been investigated by hncar reactor-infrared matrix and microwave spectroscopy. The reaction is shown to produce formaldehyde and chloroethylcnc oxide, bcsidcs already known product. Implicationb for the reaction mcchnni\m will be discuswed.
📜 SIMILAR VOLUMES
The rate law -d[O,]/dt = kl[A][OJ + k3[A][03]2/(k4 + kb[02]) has been found to obrain for the reaction of ozone with allene and with 1,2-butadiene. We now find that this rate law also applies to the reaction of ozone with ethylene and presumably with all lower alkenes. This generalizes the inhibiti
The reaction between ozone and thiophene was studied from 30 to 125°C over a pressure range of 0.005-0.3 torr ozone and 0.1-1 torr thiophene. The most abundant product was 0 2 with smaller amounts of CO, and SOZ. The mass balance was 100% for oxygen and approached 100yo for sulfur a t the higher val