HF is produced vibrationally-rotationally excited in the gas phase systems F + CH 4 and F + CH2F 2. The nascent vibrational distributions observed by IR chemiluminescence for the primary hydrogen abstractions are NI:Nz:N 3 = 30 : 58 : 12 and 36 : 45 : 19 respectively, in fair agreement with publishe
Infrared emission spectroscopy in H2/F2 and CH4/F2 premixed flames
β Scribed by J. Vandooren; M. Vanpee
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 527 KB
- Volume
- 97
- Category
- Article
- ISSN
- 0037-9646
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Chemical structures of atmospheric-pressure, fuel-rich (sooting), premixed, laminar flames of 1,2-C2H4C12 and CH 4 have been investigated using a flat-flame burner. Species mole fraction profiles were determined by using a hot-water-cooled micro-probe coupled to an on-line gas chromatograph/mass spe
2-fluorovinyl radicals were generated in solid argon by solid-state chemical reactions of mobile F atoms with acetylene and its deuterated analogues. Highly resolved EPR spectra of the stabilized radicals CHF&dbond(\*)CH, CDF&dbond(\*)CD, CHF&dbond(\*)CD, and CDF&dbond(\*)CH were obtained for the fi
High-resolution, infrared absorption spectra of the 6 (asymmetric C-H stretch) and 2 2 (H-C-H symmetric bend overtone) bands of jet-cooled CH 2 F 2 are reported with a sub-Doppler resolution of Ο³0.002 cm Οͺ1 . More than 600 transitions were observed in the range of 3002-3036 cm Οͺ1 , of which 268 were