The infrared diode laser spectrum of the n 2 / n 5 0 n 2 hot band of acetylene has been observed within the discharge plasma of acetylene diluted in He. The concentration of acetylene in the n 2 state was modulated by applying a few kHz of ac current, and the spectrum of the hot band was recorded se
Infrared Diode Laser Spectroscopy of the ν1Fundamental and ν1+ ν5− ν5Bands of the C3S Molecule
✍ Scribed by Shuro Takano; Jian Tang; Shuji Saito
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 157 KB
- Volume
- 178
- Category
- Article
- ISSN
- 0022-2852
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✦ Synopsis
The vibration-rotation absorption spectra of the C 3 S molecule were studied using a tunable infrared diode laser spectrometer. The n 1 fundamental and n 1 / n 5 0 n 5 hot bands were measured between 2046 and 2067 cm 01 . The C 3 S molecule was produced by a glow discharge in a flowing mixture of CS 2 , C 2 H 2 , and He. The analysis of the measured spectral lines yielded the band origins, the rotational and centrifugal distortion constants in the upper vibrational states, and the l-type doubling constant for the n 1 / n 5 state. The band origins were determined to be 2058.21875(47) and 2053.03769(45) cm 01 for the n 1 fundamental and n 1 / n 5 0 n 5 bands, respectively. The values in the parentheses correspond to three standard deviations.
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