𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Infrared dichroism and molecular conformation of α-form poly-γ-benzyl-L-glutamate

✍ Scribed by Tsubio, Masamichi

Publisher
John Wiley and Sons
Year
1962
Weight
680 KB
Volume
59
Category
Article
ISSN
0022-3832

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Precise measurements were made of the dichroic ratios of several absorption bands of α‐form poly‐γ‐benzyl‐L‐glutamate. From the results obtained, directions were determined for the transition moments of these bands, and possible orientations are given for the peptide, ester, and phenyl groups in the polymer with respect to its fiber axis. On the basis of these orientations a model is proposed for the molecular conformation of this polypeptide.

📜 SIMILAR VOLUMES

The infrared electric dichroism of poly-
The infrared electric dichroism of poly-γ benzyl-L-glutamate solutions
✍ J.V. Champion; J.W. Nicholas 📂 Article 📅 1972 🏛 Elsevier Science 🌐 English ⚖ 298 KB

Xleasuremcnts of the infrared electric dichroism of the perpcndicuiar branch of the amide II band of poly-y-benzyi-L-glutamate in dioxan at 1550 cm -' xc dcscribcd. Polydispersity of the Qmple and flexibility of the rigid rod for the model of the helix sonformation ;LX ncccssxy postulates to obtain

Vibrational circular dichroism of poly(γ
Vibrational circular dichroism of poly(γ-benzyl-L-glutamate)
✍ R. D. Singh; T. A. Keiderling 📂 Article 📅 1981 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 218 KB 👁 1 views

Vibrational circular dichroism (VCD), the differential absorption of circularly polarized light by vibrational transitions, is a new technique of potential use for stereochemical analysis.13 Recent instrumental developments have allowed extension of the VCD technique down to 1250 cm-l, thereby encom

Rotatory dispersion and circular dichroi
Rotatory dispersion and circular dichroism of low-molecular-weight poly-γ-benzyl-L-glutamate
✍ Toyoko Imae; Shoichi Ikeda 📂 Article 📅 1972 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 393 KB 👁 1 views

## Synopsis llotatory dispersion and circular dichroism of low-molecular-weight poly-7-benzyl-Lglutamate, which was prepared from the ,V-carboxyanhydride by n-hexylamine initiation a t [A]/[I] 3, 4, and 8, have been nieasured in ethylene dichloride and dioxane a t difierent concentrations. The rot

Aggregation of poly(γ-benzyl-α,L-glutama
Aggregation of poly(γ-benzyl-α,L-glutamate)
✍ Sumana Chakrabarti; Wilmer G. Miller 📂 Article 📅 1984 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 812 KB

## Abstract The aggregation of poly(γ‐benzyl‐α,L‐glutamate) and its enantiomer in toluene has been investigated by following the viscosity as a function of temperature, concentration, molecular weight, molecular‐weight distribution, helix chirality, and shear rate. The temperature and concentration

The β-conformation and association of lo
The β-conformation and association of low-molecular-weight poly-γ-benzyl-L-glutamate in Solutions
✍ Shoichi Ikeda; Toyoko Imae 📂 Article 📅 1972 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 701 KB

Three samples of poly--phensyl-L-glutamate have been prepared from r-henzyl-,Vcarhoxy-L-glutamate anhydride with n-hexylamine initiation a t anhydride-to-initiator molar ratios, [A]/[I], of 3, 4, and 8, and their conformation and association in ethylene dichloride and dioxane have been investigated