Infrared Chemiluminescence Study of the Reactions of Hydroxyl Radicals with Formaldehyde and Formyl Radicals with H, OH, NO, and NO 2
β Scribed by Butkovskaya, N. I.; Setser, D. W.
- Book ID
- 126947895
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 203 KB
- Volume
- 102
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
The reactions of N,O with NO and OH radicals have been studied using ab initio molecular orbital theory The energetics and molecular parameters, calculated by the modified Gaussian-2 method ( G 2 M ) . have been used to compute the reaction rate constants on the basis of the TST and RRKM theories Th
## Abstract The rate constants for the reactions magnified image have been measured directly by flash photolysis and kinetic spectroscopy. At room temperature, __k__~3~ = (3.4 Β± 0.1) Γ 10^9^ L/molΒ·s, independent of pressure in the range of 55β400 torr, and __k__~6~ = (2.1 Β± 0.2) Γ 10^9^ L/molΒ·s.