Infrared and spectra of some trihalide ions: ICl−2,IBr−2, I−3, I2Br−, and BrICl−
✍ Scribed by A.G. Maki; R. Forneris
- Book ID
- 113371573
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- English
- Weight
- 753 KB
- Volume
- 23
- Category
- Article
- ISSN
- 1386-1425
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The kinetics of the title reactions have been studied using the discharge-flow mass spectrometic method at 296 K and 1 torr of helium. The rate constant obtained for the forward reaction (1), using three different experimental approaches (kinetics of Br Br ϩ IBr : I ϩ Br 2 consumption in excess of
The small hser pulse gavl method, based on photochcmlal Br and I hscts, 15 used to probe 'P,,, nnd 2P,,2 stata of iodmc and bromine aloms in the rcncllons F + Br2 -Brr + Br (I). l('Pt,z) + Brz -IBr + Br (Il),and Br + Itcr -Br2 + I (III) The results obtained arc upablc of formuhtmg B conscrvstlon ru