The infrared and Raman spectra of polycrystalline were recorded at 77 and 10 K, respectively. (CH 3 ) 3 CCCH Crystal splittings were observed for some of the fundamentals and possible crystal structures are discussed. Anomalous band shifts between the liquid and solid state spectra were noted for bu
Infrared and Raman Study of Solid Dibromodichloromethane
β Scribed by T. D. Huynh; A. Anderson
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 227 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0377-0486
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β¦ Synopsis
Infrared and Raman spectra of solid dibromodichloromethane at temperatures between 12 K and the melting point are reported. All nine internal modes are observed with both techniques. Multiple components of some modes are attributed to isotopic species. The absence of crystal Γeld splittings and of lattice spectra with strong, sharp peaks at low temperatures is compatible with a crystal which has locked-in orientational disorder, as suggested by recent heat capacity measurements.
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