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Infrared and Raman studies of TTM-TTP and TSM-TTP charge-transfer salts

✍ Scribed by R Świetlik; K Yakushi; K Yamamoto; T Kawamoto; T Mori

Book ID
104059898
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
155 KB
Volume
704
Category
Article
ISSN
0022-2860

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✦ Synopsis

We measured room temperature infrared and Raman spectra of the neutral TTM-TTP molecule and four conducting charge-transfer salts: (TTM-TTP)I 3 , (TTM-TTP)AuI 2 , (TTM-TTP)(I 3 ) 5/3 and (TSM-TTP)(I 3 ) 5/3 . The vibrational bands related to the CyC stretching modes were analysed. The frequencies of CyC stretching modes observed both in infrared and Raman spectra depend linearly upon the charge on TTM-TTP (or TSM-TTP) molecules.

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