Infrared and Raman studies of the Verwey transition in magnetite
✍ Scribed by Gasparov, L. V.; Tanner, D. B.; Romero, D. B.; Berger, H.; Margaritondo, G.; Forró, L.
- Book ID
- 121423176
- Publisher
- The American Physical Society
- Year
- 2000
- Tongue
- English
- Weight
- 100 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1098-0121
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## Abstract The Verwey transition in magnetite is investigated using a band model with interatomic Coulomb energy introduced by Cullen and Callen. This model is treated in the Hartree‐Fock approximation. A tight‐binding calculation of the band structure with Verwey ordering yields a gap in the sing
By combining ab initio results for the electronic structure and phonon spectrum with the group theory, we establish the origin of the Verwey transition in Fe 3 O 4 . Two primary order parameters with X 3 and 5 symmetries are identified. They induce the phase transformation from the high-temperature