Infrared and raman spectra of moderatively strong hydrogen-bonded liquids. Effect of electrical anharmonicity upon profiles of hydrogen-stretching bands

Theory of profiles of hydrogen stretchin

Theory of profiles of hydrogen stretching infrared bands of hydrogen-bonded solids. Model of strong coupling between the high-frequency hydrogen stretching vibration and low-frequency phonons

✍ Henryk Ratajczak; Anatolij M. Yaremko 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 388 KB

A theory is developed to describe a broad IR absorption which appears in the range of a high-frequency stretching vibration of the X-H group involved in the hydrogen bond in solids. The theory is based on the anharmonic coupling mechanism between the high-frequency hydrogen stretching vibration, v(X