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Infrared and Raman spectra and normal coordinate analysis of disilylchloride

โœ Scribed by A.Ben Altabef; R. Escribano

Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
709 KB
Volume
47
Category
Article
ISSN
1386-1425

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โœฆ Synopsis

Disilylchloride has been synthesized by chlorination of disilane with boron trichloride. FTIR spectra have been obtained of the vapour phase and Rarnan spectra of the liquid phase of this molecule. The spectra are fully assigned for the first time. A normal coordinate analysis is carried out and the refined force constants are compared to previous works on disilane, disilyliodide and silylchloride. The height of the potential energy barrier to internal rotation in disilylchloride is also evaluated.

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Raman and infrared spectra, ab initio ca
Raman and infrared spectra, ab initio calculations and normal coordinate analysis of boranedimethyl sulfide
โœ K. K. Chatterjee; J. R. Durig ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 447 KB ๐Ÿ‘ 1 views

## Abstract The Raman spectra (3200โ€40 cm^โˆ’1^) of liquid and solid boranedimethyl sulfide, (CH~3~)~2~SBH~3~, were recorded and depolarization data were obtained from the liquid. Additionally, the infrared spectrum (3200โ€400 cm^โˆ’1^) of the liquid was obtained. A complete vibrational assignment is pr