Using the scaled quantum-mechanical SQM force field approach with direct scaling of individual primitive force constants, we derive optimal scaling factors by a least-squares fit to the experimentally observed fundamentals of some selected ''simple'' fluorocarbons. We use the derived scaling factors
β¦ LIBER β¦
Infra-red spectra, vibrational assignments, and force constants of some monohalogeno diacetylenes, including force constants of some halogeno cyanoacetylenes
β Scribed by P. Klaboe; Else Kloster-Jensen; S.J. Cyvin
- Book ID
- 113371718
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- English
- Weight
- 664 KB
- Volume
- 23
- Category
- Article
- ISSN
- 1386-1425
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AbstractIThe i.r. spectra (4000-50cm -~) and laser Raman spectra of solid K3ReO2(CN)4, K3ReO2(t3CN)4 (99Β°~ t3C enriched), and K3RetSOt60(CN)4 (20% Iso enriched) have been measured. An assignment of the vibrational frequencies for the D4h ion has been made. A normal coordinate analysis was carried ou