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Information transfer in calix[4]arenes: influence of upper rim substitution on alkaline metal complexation at the lower rim

✍ Scribed by Daniel T. Schühle; Sascha Klimosch; Jürgen Schatz


Book ID
108285133
Publisher
Elsevier Science
Year
2008
Tongue
French
Weight
181 KB
Volume
49
Category
Article
ISSN
0040-4039

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A comparative study on a series of penta-O-alkylated p-H-calix[5]arenes lb-e and p-tertbutylcalix[5]arenes lg-m shows that the former are inherently mobile and adopt in solution non-cone conformations. The 1,2-alternate conformation for penta-O-benzyl ether lc was proven by single-crystal X-ray anal