## Abstract Nucleation characteristics of isotactic polypropylene (iPP) nucleated by the α/β compounded nucleating agents (NAs) were investigated by wide‐angle X‐ray scattering, differential scanning calorimetry and mechanical testing. The results showed that the nucleation effect of the α/β compou
Influence of β-nucleating agent on the mechanics and crystallization characteristics of polypropylene
✍ Scribed by Puyu Zhang; Xiaoxia Liu; Yongqiang Li
- Publisher
- Elsevier Science
- Year
- 2006
- Tongue
- English
- Weight
- 109 KB
- Volume
- 434
- Category
- Article
- ISSN
- 0921-5093
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✦ Synopsis
Commercial-grade isotactic polypropylene (iPP) was modified with a specific acylamino-nucleator (-nucleator) in concentrations from 0.1 wt.% to 0.5 wt.%. The mechanical properties of -nucleated polypropylene were studied. The results showed that the -nucleating agent had outstanding properties in increasing the toughness of iPP. The impact strength rised to 67.76 J/m 2 from 36.09 J/m 2 original, elongation at break of iPP was improved from 499% to 144% by adding -nucleating agent. The reason of the increase of mechanical properties has been ascribed to a specific structure of the amorphous tied-molecule induced by the presence of the -nucleating agent. The nonisothermal crystallization behavior of iPP and -nucleated iPP were studied by means of differential scanning calorimetry (DSC).
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The isothermal and nonisothermal crystallization kinetics of nonnucleated and nucleated isotactic polypropylene ( iPP ) were investigated by DSC and a polarized light microscope with a hot stage. Dibenzylidene sorbitol ( DBS ) was used as a nucleating agent. It was found that the crystallization rat
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