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Influence of α-CF3 and β-CF3 substituents upon the basicities of aliphatic amines

✍ Scribed by I.N. Rozhkov; N.M. Karimova; Yu.L. Ignatova; A.G. Matveeva; Yu.A. Borisov

Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
42 KB
Volume
54
Category
Article
ISSN
0022-1139

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## Abstract Rate constant ratios, __k__~d~/__k__~c~ for the disproportionation/combination reaction have been measured as 0.07 ± 0.02 when an H is removed from the CH~2~ position of the CF~3~CH~2~CHCH~3~ radical and as 0.24 ± 0.03 when the H is removed from the CH~3~ position in the reaction with t