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Influence of water-soluble sulfonated phosphine ligands on ruthenium catalyzed generation of hydrogen from formic acid

✍ Scribed by Gan, Weijia; Fellay, Céline; Dyson, Paul J.; Laurenczy, Gábor


Book ID
120285926
Publisher
Taylor and Francis Group
Year
2010
Tongue
English
Weight
377 KB
Volume
63
Category
Article
ISSN
0095-8972

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✍ Marı́a A. Busolo; Francisco Lopez-Linares; Antida Andriollo; Daniel E. Páez 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 89 KB

The regioselective catalytic hydrogenation of benzo [b]thiophene (BT) and quinoline (Q) were carried out in a biphasic (water/decalin) medium using two ruthenium(II) complexes as catalyst precursors. These water soluble complexes were of the type RuHCl(TPPTS) 2 (L) 2 , (where L = 1,2,3,4-tetrahydroq