Influence of trivalent cation doping on the ionic conductivity of KTiOPO4
✍ Scribed by Tom Hörlin; Rindert Bolt
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 656 KB
- Volume
- 78
- Category
- Article
- ISSN
- 0167-2738
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## Abstract Pyrochlore oxides of __A__~2~Zr~2~O~7~, where __A__ represents trivalent rare‐earth elements, have a high electrical conductivity, which makes them suitable for applications as high‐temperature solid electrolytes. The influence of Gd and Yb cations co‐doping at the Nd site on structure
Electronic and structural in6uences on ionic conductivity in the crystalline lithium phosphorus oxynitrides -Li 3 PO 4 and Li 2.88 PO 3.73 N 0.14 are analyzed, using approximate molecular orbital calculations. Starting from -Li 3 PO 4 , we construct a model compound for the new nonstoichiometric oxy